Can't believe this hasn't been posted yet. Glad to be the one. Annual tomato fight lasting about two hours. The last Wednesday of August. About 10.30 in the morning. Bring old clothes, a change of clothes and a disposable camera. That's all I can say. Just go.
In the town of Bunol, about an hour west of Valencia on the train. Just get yourself to the train station in Valencia early in the morning. Follow the crowds;
www.thisisvalencia.com/thetomatinafesti.html
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